Defending champion Djokovic faces Thompson on Wednesday, and though the odds will be heavily stacked in the Serbian's favour, his 70th-ranked opponent has an ace up his sleeve, having consulted with Kyrgios ahead of the second-round clash.
"Nick's beaten him a couple of times," Thompson told reporters on Monday.
It's not every day you play Novak at Wimbledon.
Third seed Daniil Medvedev and fifth seed Stefanos Tsitsipas will also complete their postponed first-round matches.
Women's top-10 seeds Maria Sakkari, Petra Kvitova and Barbora Krejcikova will play their opening matches of the tournament.
Persons:
Novak Djokovic, Nick Kyrgios, Jordan Thompson's, Djokovic, Thompson, Nick's, Nick doesn't, It's, Novak, Casper Ruud, Andrey Rublev, Stan Wawrinka, Daniil Medvedev, Stefanos, Iga Swiatek, Sara Sorribes Tormo, Victoria Azarenka, Caroline Garcia, Maria Sakkari, Petra Kvitova, Barbora, Aadi Nair, Toby Davis
Organizations:
Wimbledon, Djokovic, All England, Britain's Met, Thomson
Locations:
Tunisian, French, Bengaluru