The more emitters have to pay for EU carbon permits to cover each tonne of C02 they produce, the greater the incentive to invest in low carbon technologies and switch to less polluting fuels.
Still, rising carbon prices are a cause of political tensions in the EU and breaching the 100 euro threshold is likely to reignite debates over prices.
Spanish Prime Minister Pedro Sanchez last year called for a CO2 price cap to help tackle soaring inflation.
Other EU countries view a robust carbon price as vital to meeting climate goals.
Years of weak prices followed until CO2 prices began to recover in 2018 when the EU agreed to remove surplus permits from the market.